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Quick market entry with partner Symbio

Quick market entry with partner Symbio

In June 2022, automotive supplier Schaeffler together with Symbio – a Michelin and Faurecia company – established the joint venture Innoplate which plans to produce “the next generation” of bipolar plates. Benjamin Daniel, head of the fuel cell business unit at Schaeffler Automotive Technologies, explains the new options.

H2-international: Bipolar plates are considered a strategic component in a fuel cell system. At Schaeffler how do you tackle the challenges of their production? Which areas of expertise do you bring to this?

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Daniel: The ability to mass-produce components such as bipolar plates efficiently and economically is essential for the large-scale deployment of fuel cell systems. This industrialization is at the heart of Schaeffler’s strategy and is an important part of the 2025 road map. It allows an overall reduction in the cost of fuel cell stacks and systems. As a world-leading automotive and industrial supplier we have extensive expertise in precision forming and punching technology as well as a deep knowledge of the processes involved in the mass manufacturing of metal bipolar plates. We use this experience both for electrolysis and as a key element in fuel cell stacks. Schaeffler’s high degree of vertical integration with regard to forming technology and its sophisticated coating processes form the basis for a sound understanding of mass production processes for bipolar plates.

What role does your joint venture with Symbio play here?

Together we see enormous potential in the developing hydrogen economy. The establishment of this Franco-German project will also strengthen the European value chain for hydrogen-based mobility. By the end of the year we will be starting joint venture operations under the Innoplate brand and pushing the production of next-generation bipolar plates for the entire market for proton exchange membrane fuel cells. As a result, customers will benefit in future from increased performance, larger capacities and a lower price. In addition, the joint venture allows us to quickly enter the market with a leading fuel cell provider as a partner.

What’s the current situation and what will the next steps be?

At the moment we’re developing the manufacturing processes in our center of excellence for hydrogen technology in Herzogenaurach and are establishing production at the joint venture site in Haguenau in France. At first we want to make 4 million bipolar plates a year at the production site in Haguenau, with the aim of producing around 50 million plates annually by 2030. By that time we expect there to be 120 members of staff working in this area. The joint venture’s customers are Schaeffler and Symbio. Symbio has already received its first order as a major fuel cell system supplier from a leading vehicle manufacturer. It’s envisaged that the joint venture will produce the bipolar plates for the order.

Author: Michael Nallinger

Efficient coating process for BPPs

Efficient coating process for BPPs

In PEMECs (proton-exchange membrane electrolyzers) as well as PEMFCs (PEM fuel cells), chemical processes are taking place during operation that attack the surface of the material used and lead to corrosion in the medium or long term. Various studies show that because of internal corrosion processes in BPPs (bipolar plates) made of pure stainless steel, the, for example, target fuel cell service life of at least 10,000 operating hours in passenger cars is difficult to reach. Fuel cells for heavy-duty applications or for electrolyzers in continuous operation demand much longer lifetimes.

PVD (physical vapor deposition) coating, a technology used for decades for a variety of applications, presents a solution to this problem. “Through suitable coating of the two outer sides of BPPs, their corrosion behavior under long-term operation and thus their service life can be significantly optimized,” says Dr. Andreas Kraft, Director of Operations at PVT (Plasma und Vakuum Technik GmbH). According to him, this does not result in any loss of conductivity, but even rather an improvement towards a desired high conductance value. The company with headquarters in Bensheim, near Frankfurt am Main, has been operating in the field of ion- and plasma-assisted PVD coating of tools and components for more than 35 years.

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The coatings that are applied to the BPP, although very thin, constitute a major cost factor in the manufacture of the plates. “For a plate with a size of about 750 cm2, the cost of coating should end up well below 1 euro per plate,” stressed Kraft. Simultaneous coating of both sides of a BPP therefore requires a highly productive coating process as well as technology that gives reliable, reproducible results. This is why, according to the materials expert, the batch coating systems typically used in tool and component coating are uneconomical in terms of productivity and do not lead to the desired results.

“For a mass production of this sort, only so-called in-line systems come into consideration, in which substrates are coated on both sides with high throughput and without rotation,” stressed Kraft. In contrast to batch systems, these are multi-chamber setups in which the substrates are transported from chamber to chamber. The chambers are separated by large transfer valves, and the spatial and temporal separation allows various defined processing steps to occur. This design allows for a clean environment with consistent vacuum and processing conditions.

With the i-L 4.3500 in-line system developed by PVT, according to Kraft, 5 million BPPs of size 500 mm x 150 mm for fuel cells can be coated on both sides in the same consistent quality. The system is realized by the combination of four individual modules, with each forming a chamber, so that BPPs could simultaneously, at different positions, be fed in (into vacuum), coated under constant vacuum conditions, and finally discharged again (back into ambient conditions).

The PVT manager stressed that the coating costs per plate for a fuel cell BPP typically end up well below 1 euro. Depending on the process and coating materials used, the costs can even turn out significantly lower, according to Kraft.

Author: Michael Nallinger

Key components with optimization potential

Key components with optimization potential

The bipolar plate is one of the most used components in a fuel cell stack, alongside the gaskets and the membrane electrode assembly. This is why it’s important in the overall scheme of things to bring down their cost. Manufacturers, regardless of whether they produce metal or graphite solutions, are increasingly looking to automate and link up individual processes on the one hand and to optimize the products themselves on the other, for instance by further reducing sheet thicknesses. Already plans are afoot to scale up production and could result in several million bipolar plates being manufactured for use in over 100,000 stacks every year.

In a proton exchange membrane fuel cell, the bipolar plate is a key component. It accounts for up to 80 percent of stack weight and up to 65 percent of stack volume, hence its enormous importance in terms of the power density. It’s equally significant for the functioning of the fuel cell: The bipolar plate or BPP separates and distributes process gases and removes product water. Not only that, this component is responsible for performing the essential tasks of conveying the generated current and evenly distributing all media.

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BPPs are principally made from graphite carbon or metal. The various materials are associated with different properties and have different advantages for plate functionality. Because of low efficiency benefits and a lack of manufacturing processes for competitive metal BPPs, it is the graphite variant that has dominated in the past. However, graphite-based BPPs exhibit volumetric and gravimetric shortfalls compared with their metal counterparts, particularly when it comes to demanding applications. Plus, graphite is extremely brittle and can therefore break easily. Nevertheless, graphite plates are frequently deployed in stationary applications in which the volume of the structure is not a limiting factor.

On matters of cost, it’s metal plates that take the lead. “With the right production process the sheet thicknesses can be reduced down to 0.05 mm. Here, metal is at a completely different price level to graphite,” emphasizes German manufacturer CellForm. Given that several hundred plates are used in a single stack, the financial ramifications for the final application are huge. A further advantage of metal BPPs cited by CellForm is their positive impact on the cold-start capability of the fuel cell.

The company, based in Baienfurt in Baden-Württemberg, covers the entire manufacturing process for metal BPPs with a multistage forming process and subsequent laser welding. Commenting on working with metal, company representatives point out that the “extremely thin” sheet thicknesses are a particular challenge: Shaping such fine initial sheets and creating the highly precise and complex geometry of the channels can, due to physical constraints, quickly lead to fractures that would render the BPP unusable. On top of this come the stringent quality requirements with low margins for error which need to be met when producing in large volumes. “Only those who satisfy this requirement will be able to maintain their position in this growing and fiercely competitive market,” says the company.

These challenges, according to CellForm, are putting a certain degree of selective pressure on the manufacturing processes which are still under development. “Physical restrictions – such as heat generation – will limit how much these processes can make in future mass production,” states the manufacturer. This problem, it says, isn’t noticeable when dealing with small volumes, but will become increasingly evident in the years ahead as demand grows.

H2-Merit Order – Future Priorities for supplying H2-energy

H2-Merit Order – Future Priorities for supplying H2-energy

A full decarbonization of the European energy supply to achieve the 1.5 °C target from the Paris agreement is not a question of “if” but of “how”. In particular, the European Green Deal envisages climate neutrality by 2050 based on renewable energy sources (RES) as top priority of its political agenda for the coming decades [1]. What is more, the International Energy Agency (IEA) promotes a radical paradigm change of the global energy supply in favour of RES [2]. In Germany, a foregoing climate policy has been fortified by the federal German Constitutional Court’s groundbreaking verdict to introduce more stringent climate policies as a reaction to several constitutional complaints against failing climate policy. In the Netherlands, the local Den Haag Court of Justice has ruled that Shell shall amplify its CO2-emission reduction measures in its global operations [3] [4] [5].

Both the European Commission and the IEA underpin that hydrogen should gain a key role in the power sector as well as in all other energy sectors on the way towards zero CO2 emissions [1] [2]. Hydrogen can be easily stored in large quantities for long periods of time and used for re-electrification in corresponding power plants. In this way, it can contribute to integrate intermittent renewable power into the energy system [2].

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In this context, an important question referring to the optimal mix for hydrogen production has yet not been answered: from which energy sources and in which world regions shall (green) hydrogen be produced and what are relevant corresponding international strategies? From the German and European perspective, multiple hydrogen supply options could be chosen from as hydrogen is a universal energy carrier which can be produced by different and in the future more decentralised technologies around the globe [6] [7].

Multiple hydrogen production options

Following the official terminology of the European Commission concerning different production pathways [8], hydrogen is classified as “fossil-based H2” and “electricity-based H2”, distinguished by primary energy input (e.g. natural gas, mineral oil or electricity) and the respective key production technology. These two classes are subdivided into “low-carbon H2” (incl. “fossil-based H2” with carbon capture as well as “H2 from electrolysis with electricity from grid or nuclear electricity”) on the one side and “renewable or clean H2” through electrolysis with renewable electricity (REN-E) on the other side. In addition, the following terms are being used:

  • Green hydrogen (electrolysis based on renewable electricity or gasification of biomass),
  • Blue hydrogen (traditional process from fossil energy with carbon capture and storage – CCS),
  • Turquoise hydrogen (methane pyrolysis),
  • Yellow or red hydrogen (electrolysis based on nuclear electricity) and
  • Grey hydrogen (traditional processes without CCS or electrolysis based on grid electricity).

The structure of terms and the colour coding are depicted in Figure 1.

Traditional production technologies

The traditional hydrogen production technologies belong to the group of fossil-based processes, today typically dominating global bulk hydrogen production. Steam reforming of natural gas or methane (SMR) is the principal process technology (catalytic, endothermal) in (chemical) industry which requires steam as single additional feedstock and with highest efficiencies in large plants. Worldwide, about 2% of global coal and 6% of global natural gas consumption is used for hydrogen production, out of which 73 MtH2/a are converted to pure hydrogen and a further 42 MtH2/a blended with synthesis gases [6].

Another similar and widely applied industry process technology is dubbed partial oxidation of heavy fuel oil (POX), which requires oxygen as feedstock (non-catalytic for sulphur-containing fuels, exothermal). It is applied in locations where cheap heavy fuel oil (HFO) is available such as in oil refineries. By combining both processes through adjusting a stochiometric equilibrium of steam and oxygen feeds, the highly dynamic autothermal reformation process (ATR) has been developed for e.g. natural gas as feed at a somewhat reduced overall efficiency (65% instead of the up to 80% of SMR). Another advantage of this technology is that the resulting synthesis gas has high hydrogen contents.

 

Furthermore, the reaction is energy neutral, i.e. neither auxiliary thermal energy is required nor waste- or off-heat need to be considered, allowing a robust process design (Table 1). With the goal to substitute fossil by renewable energy according to emission reduction targets, SMR, POX and ATR will only contribute temporarily. Both regional and logistic aspects have to be considered in assessing an economic competitiveness of fossil hydrogen over time, and the degree to which CO2 can be taken out of the atmosphere at the given and measurable scale.

All fossil processes are characterised by highest efficiencies at large plant scales even though there is a small market for decentral yet less efficient methane steam reformers today. Nevertheless, the current hydrogen supply is dominated by the delivery (merchant hydrogen) or production of large hydrogen quantities onsite.

Tab. 1: Key data of the most relevant hydrogen production technologies

H2-class

Technology

TRL1
[1-9]

Costs
(2030)
[€/kgH2]

Efficiency
(LHV2)
[%]

CO2-emissions
[gCO2/kWhH2]

Operating
temperature
[°C]

Fossil-based H2

SMR

9

1.5 – 63

65 – 803

310 – 4003

700 – 800

POX

9

1.5

69

1,300

ATR

9

1.5

65

850 – 1,300

Pyrolysis4

3 – 7

2.5 – 7

30 – 60

190 – 230

600 – 1,600

Renewable
or clean H2

Gasification
of biomass

7

3 – 5.53

45 – 703

40 – 903,5

T-Bandwidth6

PEMEL

8 – 9

3 – 6.57

59 … 71

08

50 – 100

AEL

9

3 – 6.57

58 … 67

08

70 – 90

SOEL

5 -7

>80

08

700 – 900

1 TRL – Technology Readiness Level; 2 LHV – Lower heating value; 3 Depending on plant scale; 4 Bandwidth depending on technology; For larger plants also depending on transport distances for biomass; 6 The reaction zone comprises a temperature bandwidth [10]; Strongly dependent on electricity supply costs; 8 Only for full renewable electricity utilization

Pyrolysis, electrolysis and biomass-gasification

Another fossil energy based hydrogen production technology – undergoing commercialization since only recently – is the so called methane pyrolysis. It comprises a class of process technologies of its own, all having a high specific energy input in common. Possible concepts are the electric arc or microwave plasma processes (using direct electricity as energy input) or the energy contained in part of the methane feed to heat a (catalytic) moving reaction bed reactor at very high temperatures crushing the remaining methane share into its constituents hydrogen and carbon. On the one hand, an advantage of all pyrolysis based processes is solid carbon as final product instead of gaseous – and hence difficult to handle – CO2. If applied well, solid carbon can be re-utilized in a way that no CO2 is released to the atmosphere in any of the consecutive processes. On the other hand, the pyrolysis process is highly dynamic and difficult to control, i.e. it is not as robust as SMR. Finally, also the solid carbon markets are rather limited seen from an energy market scale perspective.

The key technology for green hydrogen production is electrolysis. It comprises a group of technologies, splitting water into its constituents hydrogen and oxygen using electricity as energy input. The proton exchange or membrane technology (PEMEL) applies solid proton conducting membranes whereas alkaline electrolysers (AEL) use caustic soda in an internal electrolyte circulation loop and as gas carrier. Both technologies are operated at low temperature in opposite to the high temperature or solid oxide electrolysis (SOEL) using a steam feed at up to 850°C. SOEL apply solid anode and cathode layers, plated on a gastight ceramic carrier substrate. The Anion-Exchange-Membrane Electrolysis (AEMEL) has begun to be offered in the market only recently and currently in small numbers. It promises however to be comparatively cost efficient as the use of Pt-group catalysts is avoided and at the same operational dynamics as PEM electrolysis.

Another relevant green hydrogen production pathway is the gasification of biomass or biogenic residues applying steam in an allothermic process (Güssing principle) [10]. As compared to low temperature AEL and PEMEL this technology has not been widely commercialized yet. Furthermore, its wide application is hampered by the limitation of available biomasses or (non-)organic residues in Europe.

Beyond hydrogen from electrolysis, it may also be produced through further green hydrogen production pathways (see Fig. 2). A thorough assessment of 10 process technologies found, however, that most of the alternative options are limited by either region specific advantages or are at a very early research or development stage

 

 

Other term widely used today is “by-product H2” The term is applied to (chemical) processes (e.g.in refineries) in which hydrogen is produced “inadvertently” and can be made readily available at low cost in large quantities. As today’s by-product hydrogen is generated through fossil based processes it is in principle also denoted as grey hydrogen, i.e. characterized by similar specific CO2 emission levels.

Depending either on production technology or customer specific quality requirements, the hydrogen delivered has to be purified by a set of gas cleaners designed to meet the relevant end-user needs by impurities, process layout and plant scale. Typically and according to recent agreements by European gas industry, this will comprise industry grade hydrogen in dedicated hydrogen transmission grids or fuel cell grade hydrogen with a very low level of hydrogen impurities

Natural hydrogen has been dubbed as “white” and is not industrially applied today. As its exploitable potentials are limited in view of the energy markets, white hydrogen from indigenous sources such as from Africa or Brazil is believed to have little impact on the development of future hydrogen energy markets, even though further analysis is being undertaken [11] [12] [13].

Power-to-X as major ingredient for renewable hydrogen production

Water electrolysis is the key process technology of all Power-to-X concepts which are the basis of green hydrogen supply. Power-to-X can be principally subdivided in different main pathway routes. The major concept is the one of Power-to-Gas (PtG) with its two options Power-to-Hydrogen (PtH2) and Power-to-Methane (PtCH4). Further Power-to-X concepts, extending the gas-focused energy world by other alternatives are: e.g. Power-to-Heat (PtH), Power-to-Liquids (PtL) as well as Power-to-Chemicals (PtCh). With the exemption of PtH, all concepts are unified by the common and central hydrogen molecule [14].

A major consequence is that electrolysis is seen as key technology for the future sustainable energy supply, with high electrical efficiency at all scales, large and small. This is the consequence of electrolysis being a surface-driven process for which only the balance-of-plant equipment’s efficiency does not scale linearly, and in contrast to volume-driven processes which are characterised by significantly increasing efficiencies towards larger process scales. The underlying argument is that today’s fossil or nuclear primary energies will be substituted by electrons as major primary energy source. Electrolytic hydrogen can thus contribute to seasonal energy storage at large scale and supplement the short-period local energy storage of electrons in mechanic-kinetic (e.g. flywheel) or mechanic-potential (pumped hydro storage) or electrochemical storage (e.g. batteries) systems. A side-effect is the substitution of a large number of aboveground electricity transmission lines with large specific footprint by cost efficient and publicly acceptable underground gas pipelines with a low specific footprint.

The CAPEX-dominated costs and resource-intense application of large-scale electricity transport and storage will thus be pushed towards OPEX-dominated costs, combined with the high energy-density gas transport/storage. With a view to water intensity, electrolysis consumes about 9 kg of water per kg of hydrogen, a factor asking for monitoring in the future. This poses no substantial challenge for central Europe (e.g. a long-term production of 100-400 TWhH2/a of hydrogen for the case of Germany would require the provision of ca. 27-108 Mt/a of water, equivalent to about 0.7-3.0% of all German drinking water needs today). In addition, it should be born in mind that water after thermal use in fuel cells becomes part of a natural water recirculation, even though locally uncoupled in case of large scale hydrogen imports.

International hydrogen production strategies

Several strategic considerations accompany the techno-economic aspects of introducing hydrogen into the energy system at large scale. In general, they strongly depend on regional framework conditions in different countries and specifically the individual strategic energy and industry policy targets, climate policy ambitions or availability of natural energy or material resources as well as societal development ambitions. Typically, these aspects are reflected in the national hydrogen strategies, being developed by different countries worldwide [15].

In view of the international context, the strategies to introduce hydrogen as energy carrier foresee two phases (Fig. 3). The first phase until 2030 typically comprises an activation of potential H2 markets. Being a transitional phase, all hydrogen colours will typically be allowed by policy makers for cost and capacity arguments. Just a few countries with specifically large renewable energy potentials such as Spain, Portugal, Ukraine, Chile or Morocco put their focus explicitly only on green hydrogen from the very beginning. In contrast, in e.g. Japan and South Korea also grey hydrogen will contribute to the H2 production mix due to cost reduction considerations (Japan) or yet less ambitious climate policy goals (e.g. South Korea), even if it is “only” imported as grey hydrogen in short term.

In other countries with a relevant natural gas production level or well-implemented gas infrastructure such as the Netherlands, the United Kingdom (UK), Norway or Russia blue hydrogen is believed to contribute in short- and medium-term. Some countries such as Germany, the European Union (EU) and Russia have developed a technology-neutral approach open for a large variety of different options. Nevertheless, Germany plans to install an electrolysis capacity of 10 GW by 2030, and the European Union of 40 GW, giving room for an early large share of green hydrogen [8] [16].

 

Fig. 3: Hydrogen colour preferences of selected national hydrogen strategies

Long-term focus on green hydrogen

 

In the long-time perspective after 2030, the global focus visibly shifts to the production and use of green hydrogen. In particular, Germany and the European Union including most EU Member States stick out visibly in their ambition to focus on green hydrogen from renewable sources, reflecting the European zero CO2 emission policy by 2050. In this way, an attempt is made to use the many advantages of green hydrogen and to achieve several energy policy goals at the same time. On the one hand, green hydrogen can be used effectively for climate protection in sectors that are difficult to decarbonize, such as heavy-duty transport or steel industry and on the other hand, to improve the flexibility of the energy system. It can also reduce dependence on fossil fuels, promote economic growth and create new jobs [17].

 

The production of blue hydrogen shall be eventually phased-out stepwise in long-term or otherwise be marginalized. By 2030, turquoise hydrogen from methane pyrolysis is seen as a bridging technology by 2030 in the national strategies specifically in Germany and the EU. The only longer-term perspective for turquoise hydrogen has been mentioned by Russia so far [15].

 

Perspectives of a future hydrogen supply

 

In addition to the domestic production of hydrogen, also (green) hydrogen imports (or exports from countries rich in renewable energy) have gained strategic importance. Specifically countries with large industry intensity such as Germany, Japan or South Korea will depend on hydrogen imports. In contrast Australia, Chile, Portugal, Spain, Morocco or Ukraine with high solar or wind potentials, understand hydrogen as an energy carrier for renewable energy with high economic potential [15].

 

It is obvious that new energy partnerships will develop, which can be observed already today. Both bilateral agreements between individual countries as well as superordinated regional cooperations will be needed in the future. An example for the first one is the cooperation between Australia and Japan for providing grey/blue hydrogen in the short-term and liquefying and shipping it to Japan at large scale [18] [19] or the declaration of cooperation between Germany and Ukraine to develop an energy partnership focusing on hydrogen among others [20].

The second option is reflected by the extensive EU programs currently in preparation to support innovative H2-projects such as e.g. the “Important Projects of Common European Interest“ (IPCEI), aiming at explicitly strengthening the cooperation of individual member states in superregional projects [21]. As this approach is technology neutral a harmonisation process is needed in respect to hydrogen quantities, type of hydrogen carrier (either gaseous or liquefied hydrogen versus hydrogen derivatives such as methane or liquid fuels versus ammonia or methanol), hydrogen colour (i.e. remaining CO2 burden) as well as transport routes and relevant future infrastructures.

Sufficient renewable energy potentials in Europe

From the European perspective, a number of criteria and open issues will have to be respected and/or decided to clarify important aspects of a large-scale hydrogen energy infrastructure, specifically with a view to the hydrogen import/export relations. The availability of renewable electricity to produce hydrogen in the EU or in Europe, in other words the green hydrogen potential, is paramount to be assessed for a fully green hydrogen portfolio in the long-term.

According to [22] the renewable electricity production potential within EU-27 and the UK amounts to a total of about 14,000 TWhel/a, the major share contributed by fluctuating wind (ca. 9,000 TWhel/a or 64%) and solar electricity (ca. 3,700 TWhel/a or 26%). In addition, this estimate is rather conservative as further potential might become available through the use of additional areas for PV plants and so-called floating technology for wind offshore.

Putting today’s electricity demand of ca. 3.000 TWh/a into perspective, it is found that close to 80 % of the total RES potential becomes available for further electrification of the energy system, e.g. for mobility (battery electric vehicles) or room heating (electrical heat pumps) as well as for the production of green hydrogen via electrolysis (Fig. 3). In view of the 2045 policy target of climate neutrality the electricity demand for direct electricity use and hydrogen production in Europe will sum up to 5,300-6,900 TWh/a [22]. Depending on the individual scenario, this would then be less than half of the total REN-potential as explained before. Further hydrogen quantities could be added as potential imports from neighbouring countries and regions such as Norway, North Africa but also Ukraine.

 

Fig. 4: Renewable electricity potential and electricity use in Europe

The findings of the above analysis show that the renewable electricity potential in Europe is sufficient to satisfy all demand for green hydrogen. For future discussions on green hydrogen import/export, it will thus not be Europe’s renewable electricity potential becoming the ceiling for domestic production. Instead, the focus should be directed at further criteria such as technical, economic, social and strategic hydrogen supply aspects such as hydrogen cost along full supply chains, energy supply independency, local value creation, political stability, established political relationships and public acceptance.

 

Of course, this relationship does not apply to every Member State, since both the renewable energy potential and the energy demand are unevenly distributed. Countries with high energy consumption such as Germany or the Netherlands will still be dependent on imports, which can, however, be served within the EU from countries with high RES potential such as Spain, Portugal or France.

 

Advantages of a “merit order“ for hydrogen supply in Europe

In this context, the future hydrogen production mix will become an important, but currently not fully resolved aspect of future regional energy systems with hydrogen as one of major energy carriers. In contrast to natural gas, the advantage of hydrogen is that it can also be produced regionally in modular electrolysers with similar efficiency as in large electrolysers around the globe. Due to its physical properties, hydrogen is similarly well transportable and storable as methane and – depending on the electricity source – can be produced at low cost. Both aspects will become relevant for the “Merit Order” for hydrogen supply seen from a regional perspective and could virtually turn it upside down in coparison to today’s fossil and centralised energy supply system.

 

Fig. 5: Supply options for a green hydrogen “merit order“, e.g. from the perspective of Mitteldeutschland [25]

Fig. 5 illustrates considerations for a “merit order” for green hydrogen supply given different supply options for a potential case of Central Germany (Mitteldeutschland) [25]. To benefit from an individual region’s opportunities in a robust way, (green) hydrogen supply should have more than one pillar. Providing hydrogen from regional renewable electricity should have highest priority from a local value creation standpoint, supplemented by national hydrogen sources imported from renewable energy rich regions e.g. by existing or refurbished hydrogen pipeline infrastructure with the ambition to safeguarding existing assets. In the case of Mitteldeutschland this could be hydrogen from on- and offshore wind in Northern Germany (e.g. in the federal state Mecklenburg-Vorpommern) through a pipeline.

Any further hydrogen demand surpassing the available local, regional and national energy resources need to be imported from farther away locations, such as other parts of the EU (e.g. from solar or wind power in Spain) or geographical Europe (e.g. from wind in East or Northern Europe) or even outside of Europe (e.g. from solar power in North Africa) simultaneously strengthening the European wide hydrogen pipeline infrastructure.

Should even these sources not prove to be sufficient e.g. during the transition phase then green hydrogen could be imported from other international resources yet at lowest priority. The long-distance import options would contribute to establish global hydrogen partnerships and a global hydrogen market, possibly lowering the global hydrogen energy price not only for industrialized countries.

Furthermore, hydrogen production costs are not the only criterion for decisions on hydrogen supply options. Other criteria such as independence, political stability, flexibility of the energy system and local value creation will come into play. Telling from the recent national hydrogen strategies, this paradigm shift has not been well understood, such that rethinking a sustainable energy system for the future by industry and politics is overdue.

Green hydrogen as local and global opportunity

Hydrogen has been identified as a central element of a future climate neutral energy system in Europe. It will facilitate the integration of renewable electricity and improve the security of energy supply. Moreover, hydrogen will generate economic welfare and entail new jobs. Even though fossil-based hydrogen is produced at large scale already today for industrial applications renewable hydrogen has been earmarked to replace the fossil-based processes by water electrolysis from renewable electricity.

Only Power-to-X concepts will fully exploit all advantages of a hydrogen-based energy system becoming the basis for a sustainable and lasting transition of the energy system. In the transition period until 2030, also low-carbon technologies using fossil energy such as e.g. natural gas through steam reforming enhanced by CCS (blue hydrogen) or methane pyrolysis (turquoise hydrogen) in some regions will activate the hydrogen market lowering the initial cost burden to develop large-scale gas infrastructures. However, in the long term, i.e. by 2050, Europe will push towards green hydrogen.

Analysis has proven that Europe‘s renewable electricity potential is sufficient for a self-sustaining renewable hydrogen supply, which will extend the considerations of import-export relations for green hydrogen. Further criteria addressing technical, social and strategic aspects will receive growing attention. For a region-specific evaluation the so-called “merit order“ of hydrogen supply need to be developed as multi-criterion analysis. It will be focused on nearby renewable energies and fill up the gap between regionally exploitable renewable energy potential and energy demand by green hydrogen from farther away regions. This approach will help to exploit and combine the different regional strengths and opportunities of hydrogen from different world regions.

We interpret the results of a recent analysis by the International Renewable Energy Agency (IRENA) [26] as first international evidence for the expected paradigm change. In a central graph the following four aspects have been illustrated from the viewpoint of an emerging European hydrogen energy market:

  • By 2050, hydrogen will be preferably provided from renewable energy sources within Europe (4,771 PJ/a),
  • All hydrogen imported to Europe will preferably be transported cost efficiently by pipeline from neighbouring North Africa (2,382 PJ/a),
  • Whereas only small quantities of ammonia are expected to be produced within Europe (136 PJ/a), a significant percentage will again be imported from North Africa by ship (1,606 PJ/a), further yet smaller quantities also from South America and the Near East.
  • The ammonia vectors are believed not to be applied for hydrogen transport (H2 derivative), but for later end-use as base chemical and here preferably for fertiliser production.

Yet, many aspects surrounding the production of (green) hydrogen have not been finally solved and require further analysis and instruments. Among others, an international hydrogen market will need to be established with an optimum balance between domestic hydrogen production and imports. In order to integrate Power-to-X concepts into international energy markets adequate regulations will have to be developed and agreed for safe and transparent hydrogen handling (e.g. certificates of origin as suggested by the European CertifHy project [24]).

Even though CO2 emissions will become the new currency in a future energy system lock-in effects (e.g. blocking investments and trained workforce, who would develop green technologies instead) from investing in durable but non-sustainable technologies (e.g. to produce blue hydrogen) need to be avoided. Green hydrogen based on renewable energy is one of the keys to achieve the 1.5 °C target from the Paris Agreement in a sustainable, socially acceptable and cost-effective manner.

Literature: To be acquired at Hydrogeit Verlag or from the authors

  1. European Commission: The European Green Deal. COM(2019) 640 final, Brussels, December 11, 2019.
  2. International Energy Agency (IEA): Net Zero by 2050. A Roadmap for the Global Energy Sector. Paris, 2021.
  3. German Constitutional Court (BVerfG): Sentence of the Erste Senat, March 24, 2021, 1 BvR 2656/18, Rn. 1-270, March 2021.
  4. German Federal Constitutional Court (BVerfG): Verfassungsbeschwerden gegen das Klimaschutzgesetz teilweise erfolgreich. Press release No. 31/2021 from April 29, 2021.
  5. Rechtbank Den Haag: Judgement May 26, 2021. Case number C/09/571932, Cause list number HA ZA 19-379,
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With a big bang into a new era

With a big bang into a new era

The presentations of new hydrogen trucks are becoming more and more spectacular. After first Faun in Bremen and then Paul Nutzfahrzeuge in Vilshofen each introduced their new H2 trucks the June of 2022, Clean Logistics (CL) followed suit on June 23rd. Paul Nutzfahrzeuge, in a hybrid in-person/online event with much dramatic steam and music, ushered in the PH2P. Clean Logistics topped this and held races with its new fyuriant on the grounds of the local airport in front of 600 invited guests.

The interest was great – on the industry side with shipping and logistics specialists as well as on the investor side, along with the media. Everyone wanted to watch and see how the retrofitted H2 truck (tractor unit) from Clean Logistics would fare against its diesel counterpart. Long story short: In the drag race – narrated by Formula 1 commentator Kai Ebel – Swedish technology influencer Angelica Larsson, in the fyuriant, gave opponent Janina Martig, in the diesel truck, no chance.

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From HyBat-Truck to fyuriant

In the midsummer heat, the two Clean Logistics founders Dirk Lehmann and Dirk Graszt, affectionately referred to as H2D2, revealed a colorfully painted hydrogen-powered tractor unit. At their side was Dr. Klaus Bonhoff from the federal transport ministry (BMVD), formerly head of the national administrative organization for hydrogen and fuel cells (Nationale Organisation Wasserstoff- und Brennstoffzellen-Technologie, NOW). Both institutions, BMVD and NOW, have been giving support to the small business founded in the state of Niedersachsen since 2017 and thus had a large part in the bringing about of this spectacle.

Bonhoff frankly explained that we “have achieved relatively little so far in the vehicle sector.” But then he pointed out that the now presented H2 truck that came out of the NIP program HyBat-Truck was excellent and that its development had been supported with 3.3 million euros of government funding. The first talks about a truck were held with shipping specialist Dirk Graszt in 2017, and then Dirk Lehmann was brought in. Lehmann, who is actually a shipbuilder, was immediately enthusiastic about the idea of converting long-haul trucks to run on hydrogen. At the time, Lehmann was managing director of E-Cap Mobility GmbH, which electrifies, in addition to maritime vehicles, also road vehicles.

The two Dirks teamed up, and this resulted in CL. Since then, they have been working to convert conventional diesel vehicles to zero-emission H2 vehicles. After buses, the formerly small company from Niedersachsen will immediately also be pushing out 40-tonne semi-trucks for the program.

“The demand is enormous,” stated Graszt in Stade. It’s no surprise, since according to the German climate protection law (Klimaschutzgesetz, KSG), greenhouse gas emissions in the transport sector must fall to 48 percent of 2019 levels by 2030. This means that of the 340,000 trucks currently registered nationwide, around 240,000 will need to be operated climate-neutrally by then.

“We are starting with a big bang into a new era… We already have the capability to make zero-emission vehicles available on the market today. Thanks to the converting of classic diesel vehicles into emissions-free hydrogen vehicles, this is also being done in a very resource-saving way. This is how we will rapidly drive the transformation of mobility into a sustainable future.”

Dirk Graszt, CEO of Clean Logistics

New CI – new logo

During the premiere at the airport in Stade, Clean Logistics SE presented itself in a completely new design – with a new corporate identity. With a new logo and a much more internationally oriented strategy. Additionally, Lehmann said, “We’re integrating Chinese technology.” The reason for this is obvious: “They’re six or seven years ahead of us in China… Refire does fully automated series production.” These compliments were likewise returned by Audrey Ma, vice president of Refire, who said, “Clean Logistics has made history by making clean logistics accessible to the world.”

Over-length is an issue

Clean Logistics sees itself purely as an integrator. The components are purchased and brought in – whether it’s the two 120 kW capacity fuel cells from Refire or the 43-kg hydrogen tanks stacked directly behind the driver’s cabin. Although these allow a range of over 400 km (250 mi), at the same time they make the vehicle around 60 centimeters (24 inches) longer.

The result of this “over-length” is that no series approval is possible under German law and only approvals on an individual basis have been granted up to now. Not only Clean Logistics is fighting this bureaucratic imposition. Because production capacities are meant to be massively expanded in Winsen an der Luhe. In the new production hall of 10,000 m2 effective area (110,000 ft2), up to 450 vehicles a year are to leave the yard starting end of 2023.

EU type approval
The German automotive office (Kraftfahrtbundesamt) gave the Eugenius brand of the Faun Group, which was introduced in the August 2022 issue of H2-international, EU type approval, which means their vehicles are allowed in road traffic throughout the EU without additional approvals from member states. Head of development Georg Sandkühler said, “As our type approval is the first granted worldwide for hydrogen-powered commercial vehicles, it means that this type of drive has taken a big step forward overall.” However, their trucks are also not over-length, because the H2 tanks are integrated in the chassis.

It was almost exactly one year ago that Clean Logistics gave the first pyuron, a hydrogen-converted bus, to the public transit company of the Uckermark in Brandenburg (Uckermärkische Verkehrsgesellschaft, UVG). The bus has been transporting tourists in the lower Oder River Valley ever since.

Fig. 2: At the celebration of the premiere, GP Joule had a special highlight to offer. André Steinau, managing director of GP Joule Hydrogen, announced to H2-international that its parent company has reserved 40 assembly stations for 40 fyuriants: “We will solve, with the production of H2, the building of H2 refueling stations and the offering of vehicles, the well-known chicken-and-egg problem.”

Dr. Klaus Bonhoff concluded, “No truck manufacturer can afford not to build H2 trucks.”

Paul Nutzfahrzeuge
Paul Nutzfahrzeuge GmbH is comparable yet quite different. Similarly to Clean Logistics, Paul is committed to H2 trucks. “Hydrogen will prevail,” sales manager Thomas Kotowski is certain. Up to 200 km (124 mi) – no matter the tonnage – battery-electric is indeed more efficient. But for longer ranges, only retrofit or fuel cell solutions come into question for him. Larger providers like Faun (see H2-international Aug. 2022) won’t be an issue, as the Bremen-based company with its Enginius brand caters to municipal vehicles on short and medium routes, whereas Paul targets mid-weight, so 12- to 16-tonne, trucks on distribution routes. Particularly package delivery services such as Hermes and DHL are potential partners here.

“Everything that Mercedes does not build with the assembly line, we build,” Kotowski told H2-international. As a special vehicles builder, the Vilshofen-based company concerns itself with not only old-time car restorations, but also installation of alternative drive systems. Paul started in 2016 with a facility that could build 1,300 vehicles a year. In order to meet the growing demand for custom-made products, a second site is currently being prepared, which is to double the total production capacity to 2,700 vehicles per year. An initial 22 units of purely H2-run trucks are foreseen for 2022, around 150 for 2023 and 500 per year for 2025. Each at an individual workstation, mind you. “We are crafters,” says Kotowski – not without pride.

Cooperation partner Shell is contributing the H2 refueling stations. There will probably be eight in 2023. Maximator stands ready as a technology provider. Although Shell is financially strong, 3 million euros for one H2 station with two pumps makes a big dent, even when the pressure is “only” 350 bar. And if several H2 trucks are to be filled, it could quickly amount to 1 tonne of hydrogen per day that needs to flow.

Paul is also involved in the service realm. “Anything that breaks, we replace,” states the key account manager. At the same time, he points out that only trained personnel may touch alternatively powered vehicles – in view of the shortage of skilled workers, for certain a bottleneck. In addition, a workshop conversion, at around 200,000 euros, will be costly.

Author: Sven Geitmann

Market is developing really well

Market is developing really well

Dr. Werner Tillmetz has not only promoted the advancement of hydrogen and fuel cell technology for many years, he has also at various points played a decisive role in shaping it – be it as a board member of the PV and fuel cell research institute of the state of Baden-Württemberg (Zentrum für Solar- und Wasserstoffforschung, ZSW) or in the formulation of the national support program for hydrogen and fuel cell innovation (Nationales Innovationsprogramm Wasserstoff- und Brennstoffzellentechnologie, NIP). Sven Jösting, on behalf of H2-interntional, spoke with Tillmetz, who after retiring founded an H2 business network for the Lake Constance Region called h2connect.eco, and asked him for an assessment of the current developments.

H2-international: Dr. Tillmetz, you have dedicated your life to fuel cells, as people can tell from reading your wonderfully written book “Wasserstoff auf dem Weg zur Elektromobilität” (hydrogen on the way to e-mobility). Where are we today regarding fuel cells in mobility?

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Interestingly, I’ve dealt with all these topics – electrolysis, fuel cells, batteries – somewhat equally, having worked in a wide variety of companies as well as in research. Quite an exciting wealth of experience. In the case of the fuel cell in mobility, it is fascinating to follow the now very broad and worldwide industrialization. Asian companies have started series production, but also German and European companies are now very successful in this. Technologically, fuel cells are ready for the market.

You are closely connected to development at Canadian company Ballard Power – including via cooperations with Ford, Daimler, and so on. Can you briefly describe for our readers how you’d valuate Ballard today?

In the 1990s, I was one of the pioneers in actively shaping the activities at these companies. Since 2003, I’ve been following the activities very intently from the outside and still have good contacts in the scene that I stay in touch with. When judging companies such as Ballard, on the one hand there is the technological point of view. In this respect, Ballard belongs, like previously, to the leading players. However, crucial is always economic developments. Here, the quarterly reports of the various publicly listed hydrogen startups give me pause, since with very few exceptions, losses have been similar to sales in value for the last twenty years. However, the market has only really recently started to develop well, primarily driven by legislation around the world towards climate protection. The number of acquisitions and the associated valuations are also impressive.

How would you appraise battery development? Why is especially the automotive industry set on battery-electric mobility and attempting to copy Tesla?

This is quite an exciting phenomenon. In recent years, the vehicle industry has failed to continue curbing global emissions legislation. At the same time, Tesla, an initially ridiculed competitor, came to the market and increasingly took sales away from the established companies in the high-margin segments. Quick action was called for, and the strategists reflexively said to themselves, “What Tesla can do, we can do too.” In this, they overestimated themselves and underestimated Tesla.

With e-vehicles, energy consumption and charging infrastructure are decisive. Tesla has excellently mastered both, while the big car companies, for example, are trying to delegate the issue of charging infrastructure to the state and to energy suppliers. With their billions in annual profit, they could make it themselves too – but profit takes precedence.

Two other major hurdles for the battery are becoming increasingly visible: where all the raw materials are going to come from and how enough green electricity for (fast) charging can be provided to meet demand.

There are various models of how hydrogen will be brought to use in motor vehicles. For example, there are models put forth in which ammonia, methanol or hydrogen (liquid or gaseous) are directly used in the engine – without the detour via a fuel cell. How do you assess this development? Is there a winner?

In general, we should be open to technology and let the engineers develop the best solutions. The legislators should only define the guard rails such as emissions. In my view, there are two crucial issues: the efficiency of the drive system and the availability of green fuel at the “gas station.”

For the dynamic operation of vehicles, electric motors with a battery have enormous advantages – a mechanical drive cannot achieve this efficiency. The (small) battery, however, can be charged by an engine or a fuel cell during the trip (serial hybrid) and then be run at the best time.

With regard to the supplying of the fuel: Hydrogen can, ideally, be directly generated in the region or transported by pipeline from sun- and wind-rich regions to filling stations throughout Europe. For the cost-effective overseas transport of energy from the world’s many sun belts, ideal is a fuel that is liquid at ambient temperature and easy to produce: methanol. At electricity prices of less than one euro cent per kilowatt-hour, the costs for generation play a very minor role. We are still at the very beginning of a marathon run – only at the finish will the wheat be separated from the chaff.

Competition has flared worldwide. What countries do you think have the better approaches?

German and EU policy is not very well thought-out strategically and is influenced by ideology in many places. On top of that is the very discussion-happy society and grassroots democratic structures that make much very slow. On the other hand, there are excellent, creative engineers and skilled workers and a solid industrial infrastructure, especially with the many family businesses that think long-term. Asian countries often have a better thought-out strategy and are much faster to implement. Last but not least comes California, with its extreme capital and readiness to take risks – the latter seems to be lost in Germany.

Now we come to charging infrastructure: electric charging stations versus hydrogen refueling stations. What should it be, do you think? Are there any critical views or visions about this that you have?

Battery-electric vehicles are best charged when and where there is direct green electricity and the fully charged battery is sufficient for a few days of driving – even when the sun is not shining or the wind is not blowing. This can also be the case at the employer’s, for example, if they equip the parking spaces with photovoltaics or install small windmills on the roof. For all frequent drivers, city buses and transport companies, fast, flexible refueling is critical: you can fill up with green hydrogen or green methanol anytime, anywhere.

Where do you see the fuel cell going in the passenger car market? In the commercial vehicle, they’re indeed convinced that a fuel cell is advantageous over a battery for long journeys. What is the situation with passenger cars? Note there are rumors Apple could be entering the market with an iCar in 2024 that would make use of a small battery for short hauls and a fuel cell (H2) for long hauls. Do you think that’s realistic?

Modern fuel cell drives, including the tanks, are significantly lighter and smaller than a battery, for the ranges often required. The difference to the classic combustion engine is barely there. Whereas installing a battery of over 600 kilograms in a car or of up to five tonnes in a truck really makes no sense. Apple’s concept is good and is already commercially offered for the delivery vans and trucks of Renault and the Stellantis brands.

Which countries are ahead regarding fuel cells, and why?

It’s more about the companies than the countries. Both Toyota and Hyundai are taking their respective products (fuel cell system) into many applications and markets. That achieves quantity and thus reduces costs. Bosch has a powerful strategy and will supply its partners around the world very quickly. The French car companies have positioned themselves well with strategic partners. And of course so have the many Chinese companies, who will reach really large quantities the fastest.

Could you please develop a future scenario for the fuel cell and hydrogen? Where, in your opinion, do we stand today, in five years, in ten years and in 2040 in terms of hydrogen and fuel cells, but also batteries?

We are standing at the very start of a marathon. The changes will be as dramatic as they were more than a hundred years ago, when Henry Ford’s gasoline-powered carriage replaced horse-drawn carriages and the internal combustion engine completely changed the world for the next hundred years. With disruptive innovations, the changes are extremely rapid and hardly predictable, as the example of Kodak and digital photography has also shown us. The battery alone will not be the magical solution for everything, as Bosch chairman Stefan Hartung recently made very clear. To be able to get a handle on climate change at all, we need all options and, above all, more action than discussion.

What would policymakers (Germany, EU) have to do to give fuel cells and hydrogen in mobility a boost?

Be open to technology and have a holistically thought-out strategy. For this, it helps to look out of the window from time to time to see whether there is enough sun or wind to ensure the energy supply for all consumers.

Interviewer: Sven Jösting

 

Contribution to the efficiency debate

With reference to the guest opinions on e-fuels from the May 2022 issue of H2-international

“Efficiency first” or “Efficiency is key” – is what countless headlines read. This is then backed up with graphs that all suggest that battery-electric e-vehicles are dramatically better than fuel cell and hydrogen e-vehicles. And e-fuels rank far behind in last place. Often the efficiency (fuel or energy consumption) of the vehicle is then lumped together with that of the upstream chain (fuel production). A comparison with reality almost always leaves something to be desired.

Comparing the energy consumption between vehicles should actually be quite easy, if you also compare vehicles that are similar to each other. The consumption (or fuel economy) is stated in the sales prospectuses and is determined in accordance with criteria prescribed by law – unfortunately in varying units: electricity in kilowatt-hours, hydrogen in kilograms and liquid fuels in liters (or gallons), without taking calorific value into account.

The real world of consumption can be found in a thorough examination of the test reviews. There, one quickly discovers that the 20 to 30 percent advantage of battery-powered vehicles practically disappears in winter, when both the passenger compartment and the battery (for fast charging) have to be heated.

Now to the upstream chain of electricity or fuel production. Here, it is almost always assumed that the electricity to charge the battery comes directly from the photovoltaic or wind power plant. The fact that no sun shines at night, nor through rain, snow or fog, is interestingly omitted. The wind also does not always blow, especially in the South of Germany. If the electricity for charging the battery is generated via a gas turbine (efficiency: 40%) powered by natural gas, or in the future hydrogen, then hopes of first place in efficiency are quickly deflated. The direct use of hydrogen in a fuel cell vehicle makes more sense here.

This is true even if the electricity is 100 percent green. On many days in Germany, there is much more electricity from wind or sun than we need. Yet especially in the winter months, there may be no wind or sun for days. So the electricity needs to come from the wind- and sun-rich times of the year. The storage of such large amounts of energy, however, is only economically feasible with hydrogen.

Today, two-thirds of our energy supply is imported (oil, gas and coal). Although 100 percent self-sufficiency is theoretically possible in Germany, in reality it’s rather unlikely. Importing green energy from very sunny and windy regions makes a lot of sense economically. Transport via power lines will, however, be limited to certain regions such as the North Sea. Using the existing European gas grid for the transport of green energy in the form of hydrogen is more than logical. For overseas transport, liquid energy sources such as methanol or kerosene (e-fuels) are becoming unbeatably attractive. It is furthermore much more efficient to use this in the drive system than to remake electricity from it.

The green energy supply of the future, thought through to the end, is very different from what most headlines today suggest: electricity, hydrogen and e-fuels are all sensible green energy sources.

Author: Werner Tillmetz